Unit conversions, the median and absorbance
13 min
- Convert between compatible mass, volume, and amount concentration units
- Calculate the median of an ordered set of results
- Convert percent transmittance to absorbance
Try first
Get the idea
Three small calculations sit under a great deal of laboratory work: moving a result between units, finding the middle of a set of results, and reading absorbance from a photometer.
Units
A concentration is an amount of substance in a volume, and both parts of the unit can change.
- Change the volume first. A liter is 10 deciliters, so a result in mg/dL becomes mg/L when it is multiplied by 10.1
- Then change the mass with the molar mass, the mass of one millimole of the substance:
mmol/L = mg/L ÷ molar mass (mg/mmol)
Glucose has a molar mass of 180.16 mg/mmol, so 1,080 mg/L of glucose is 1,080 ÷ 180.16 = 5.99 mmol/L.
The number changes every time the unit does. A result relabeled without changing its number is off:2
- by a factor of 10 for a volume change
- by the molar mass for a mass change
Each laboratory reports in the units it has validated, with its own stated factors.
The median
Put the results in rank order and take the middle one.
- When the count is odd there is one middle value.
- When the count is even there are two, and the median is their average. For four chloride results of 98, 101, 104 and 109 mmol/L, it is (101 + 104) ÷ 2 = 102.5 mmol/L.
The median depends on rank, so one extreme result moves it far less than it moves the mean.3
Absorbance
A photometer compares the light leaving a sample with the light entering it.
- That fraction is the transmittance, T.
- The percent transmittance, %T, is 100 × T.
- Absorbance is the negative base-10 logarithm of the fraction.
A = −log₁₀(T) = 2 − log₁₀(%T)
The two forms give the same answer as long as each receives its own input:2,4
- At 10%T, T is 0.10 and A = 1.00.
- At 100%T, no light was absorbed and A = 0.
- Taking the logarithm of the percent in the first form gives a negative number, the sign that the percent went into the fraction form.
References
- Thompson A, Taylor BN. Guide for the Use of the International System of Units (SI). NIST Special Publication 811. 2008 ed. National Institute of Standards and Technology; 2008.
- Bishop ML, Fody EP, Van Siclen C, Mistler JM, Moy M. Clinical Chemistry: Principles, Techniques, and Correlations. 9th ed. Jones & Bartlett Learning; 2023.
- National Institute of Standards and Technology. Measures of location. NIST/SEMATECH e-Handbook of Statistical Methods. Accessed September 23, 2026.
- International Union of Pure and Applied Chemistry. Beer–Lambert law. In: Compendium of Chemical Terminology. 5th ed. Online version 5.0.0. International Union of Pure and Applied Chemistry; 2025. doi:10.1351/goldbook.B00626
Watch one
A glucose result is 90 mg/dL. Your laboratory's comparison table lists glucose in mmol/L with a molar mass of 180.16 mg/mmol. What is the result in mmol/L, to three significant figures?
- Change the volume: 90 mg/dL × 10 = 900 mg/L.
The answer is wanted per liter, so the volume changes from deciliters to liters first.
- Divide by the molar mass: 900 ÷ 180.16 = 4.9956 mmol/L.
Each millimole of glucose weighs 180.16 mg, so the number of millimoles is the mass divided by that.
- Round the final value to three significant figures: 5.00 mmol/L.
Rounding once, at the end, keeps the intermediate error out of the reported value.
- Check the size: 5.00 is smaller than 900, as it must be.
A molar mass above 1 mg/mmol always makes the amount smaller than the mass, so an answer larger than the mass means the mass was multiplied by the molar mass.
Your turn
Results
- Convert between compatible mass, volume, and amount concentration units
- Calculate the median of an ordered set of results
- Convert percent transmittance to absorbance
To review
3 questions from this step will come back in Review.
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